Effects of memory on the coherent scattering function of a Rouse chain
- 1 April 1981
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 74 (7) , 4106-4113
- https://doi.org/10.1063/1.441539
Abstract
Truncated continued fractions are used to form estimates of the memory function associated with the coherent scattering function of a dilute polymer solution. Calculations specific to a freely draining, Rouse chain are presented for the three lowest order approximations, namely, the memoryless single-pole ’’mean field’’ approximation and the two- and three-pole approximations. The importance of memory is assessed by comparing these results with one another and with exact numerical values of the scattering function.Keywords
This publication has 19 references indexed in Scilit:
- Coherent scattering law for dilute polymer solutions: Continued fraction formalismJournal of Polymer Science: Polymer Physics Edition, 1980
- Concentration Effects on the Dynamic Structure Factor in Polymer SolutionsMacromolecules, 1978
- Application of Cascade Theory to Calculation of Quasielastic Scattering Functions. 2. Polydisperse Branched Molecules in Dilute SolutionsMacromolecules, 1978
- Application of Cascade Theory to Calculation of Quasielastic Scattering Functions. 1. Polydisperse, Ideal, Linear Chains in Dilute SolutionsMacromolecules, 1978
- Scattering of light and neutrons in a model for superionic conductorsZeitschrift für Physik B Condensed Matter, 1978
- Optimized Rouse–Zimm theory for stiff polymersThe Journal of Chemical Physics, 1978
- Quasielastic scattering of neutrons from freely jointed polymer chains in dilute solutionsJournal of Polymer Science: Polymer Physics Edition, 1977
- Diffusion in periodic potentialsZeitschrift für Physik B Condensed Matter, 1977
- Theoretical basis for the Rouse-Zimm model in polymer solution dynamicsThe Journal of Chemical Physics, 1974
- Spectral Distribution of Light Scattered from Flexible-Coil MacromoleculesThe Journal of Chemical Physics, 1968