Crystal, molecular, and electronic structure of [Ta2Cl4(µ-Cl)4(PMe3)4]: a metal–metal single bond between eight-co-ordinate tantalum atoms
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 16,p. 1086-1088
- https://doi.org/10.1039/c39840001086
Abstract
The crystal structure of the title complex shows an MCl4M bridge across a weak Ta–Ta interaction and eight-fold co-ordination about each metal centre; an electronic structure calculation supports the existence of a σ metal–metal bond.Keywords
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