Intensities of vibronic origins in the electronic spectra of amino and aquo coordination complexes
- 1 January 1976
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics
- Vol. 72, 721-723
- https://doi.org/10.1039/f29767200721
Abstract
Comparison of the vibronic structure in electronic transitions of metal complexes with NH2 or OH2 rocking vibrational modes with that of complexes which do not have such modes, suggests that the high intensity of these modes in vibronic spectra is caused by the motion of the electron density in the lone pair orbital during the vibration.Keywords
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