Photorearrangement of a γ-butyrolactone: generation of intermediates in photochemical reactions
- 1 January 1969
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 20,p. 1164-1165
- https://doi.org/10.1039/c29690001164
Abstract
The photolysis of 6,7,8,9-tetrahydro-9-hydroxy-7-oxo-5,8-methano-5H-benzocycloheptene-10-carboxylic acid lactone yields, in addition to CO2, naphthalene, keten, 3,4-benzotricyclo[3,3,0,02,8]octan-7-one, and benzobicyclo[2,2,2]octadienone, the same products obtained from the sensitized photolysis of benzobicyclo[2,2,2]octadienone.Keywords
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