Kalium-und Tetrachloroantimon(V)-phosphate / Potassium and Tetrachloroantimony(V) Phosphates
Open Access
- 1 December 1979
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 34 (12) , 1703-1710
- https://doi.org/10.1515/znb-1979-1216
Abstract
The potassium dimethoxi-, -dimethylaminomethoxi- and -bis(dimethylamino)phosphates (1), (2) and (3) were prepared by reaction of KOH and the corresponding phosphoric esterchlorides. 2 reacts with antimony(V) chloride to yield the dimeric tetrachloro- antimony(V) dimethylaminomethoxiphosphate (4). The crystal and molecular structures of 4 and the dimeric tetrachloroantimony(V) dimethoxiphosphate (5) were determined by X-ray analysis. The vibrational and NMR spectra of 1-4 are reported and briefly discussed.Keywords
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