Cross-Interaction Constants. A Mechanistic Tool
- 1 January 1999
- journal article
- Published by Institute of Organic Chemistry & Biochemistry in Collection of Czechoslovak Chemical Communications
- Vol. 64 (10) , 1529-1550
- https://doi.org/10.1135/cccc19991529
Abstract
The cross-interaction constant, ρij, is a second derivative parameter representing a change in the intensity of interaction between the two reacting partners (or fragments) i and j in a reaction. It can be either an activation or a reaction parameter. The sign and magnitude of ρij have important mechanistic significances and are useful as a tool for the studies of organic reaction mechanism. We have presented several more important applications of the cross-interaction constants. A review with 42 references.Keywords
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