Synthesis of Orthotrithioformates and Related Compounds. Carbanion Formation and Evaluation for 1,4 Addition Reactions with α,β-Unsaturated Ketones
- 1 January 1979
- journal article
- Published by CSIRO Publishing in Australian Journal of Chemistry
- Vol. 32 (2) , 353-360
- https://doi.org/10.1071/ch9790353
Abstract
The syntheses of potential α-sulfur-substituted carbanion precursors (2a-h) are reported and the results of their subsequent reactions with strong bases are presented. The relatively stable carbanions (3a-d) were made to react with a variety of α,β-unsaturated ketones and the yields of 1,4 and 1,2 addition products were determined.Keywords
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