Abstract
Essentially exact closures are presented for the second- and third-moment rate equations for diffusion of a pollutant released at a particular time in homogeneous turbulence. The quasi-Gaussian closure is found to require addition of a down-gradient diffusion term. Explicit dependence upon the time after release is found to be retained by the highest moment gradient term. The second- and third-moment approaches are therefore concluded to be inherently incapable of accurately solving the general problem of pollutants released at different places at different times.

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