Rearrangement and novel enol-ether addition in homoproaporphines
- 1 January 1968
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society C: Organic
- Vol. 8, 1003-1005
- https://doi.org/10.1039/j39680001003
Abstract
The dienone–phenol rearrangements of the two stereoisomers (IIa) and (IIb) of 2,3,7,8,9,9a-hexahydro-6-hydroxy-5-methoxy-1-methyl-1H-benzo[de]quinoline-7-spiro-3′-methoxycyclohexa-2′,5′-dien-4′-one and the dienol–benzene rearrangement of the corresponding dienol (VIII) are described. The configurations of (IIa) and (IIb) have been assigned by chemical and spectroscopic methods.Keywords
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