Synthesis of phosphapropyne by flash thermolysis of 1-vinylphosphirane or divinylphosphine
- 1 January 1992
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 24,p. 1799-1800
- https://doi.org/10.1039/c39920001799
Abstract
The thermolysis of 1-vinylphosphirane 5 at 700°C yields phosphapropyne 7; owing to the existence of an equilibrium between divinylphosphine 6 and 1-vinylphosphirane above 500°C, the same phosphapropyne is also obtained by thermolysis of divinylphosphine.Keywords
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