The Paschen-Back Effect. I.LSCoupling; theP3D3Multiplets of Zn and Cd

Abstract
Darwin's calculations for Zeeman effect are applied to the Zn and Cd P3D3 multiplets. The frequencies and intensities thus calculated show very good agreement with the experimental values. A considerably smaller discrepancy between experiment and older quantum theory is noted for the Cd than for the Zn as should be expected because of the much larger multiplet separation in the case of the former.

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