Asymmetric intercoenzyme hydrogen transfer between NADH model compounds and flavins
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 13,p. 849-850
- https://doi.org/10.1039/c39840000849
Abstract
A chiral flavin [(S)-3-methyl-10-(1′-hydroxy-3′-methylbutane-2′-yl)isoalloxazine, (1b)] has been synthesised: hydrogen transfer to (1b) and tetra(O-acetyl)riboflavin from chiral NADH model compounds occurred in an asymmetric manner only in the presence of high concentrations of Mg(ClO4)2.Keywords
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