A new application of the tetramethylphospholyl (η5-C4Me4P)π-ligand. Synthesis of η5-tetramethylphospholyl complexes of yttrium and lutetium
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 12,p. 800-801
- https://doi.org/10.1039/c39890000800
Abstract
Reaction of lithium 2,3,4,5-tetramethylphopholide with MCl3 gives η5-(C4Me4P)2·MCl·LiCl·(solvent)2[solvent = Et2O,1,2-dimethoxyethane (DME), M = Y, Lu], which are the first reported π-heterocyclopentadienyl compounds of group 3 metals.Keywords
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