Peroxydisulphate oxidation of iron(II) complexes of substituted 1,10-phenanthrolines and related compounds
- 1 January 1966
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 1772-1775
- https://doi.org/10.1039/j19660001772
Abstract
Kinetics of peroxydisulphate oxidation of several substituted tris-1,10-phenanthroline and tris-2,2′-bipyridyl complexes of iron(II) have been studied. Activation energies and frequency factors have been determined. Substituent effects on these parameters are described, and the mechanism of the oxidation discussed.Keywords
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