Some reactions of rhenium(V) chloride
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 1617-1620
- https://doi.org/10.1039/j19700001617
Abstract
The results of some spectroscopic measurements on rhenium(V) chloride are discussed. The reactions of this chloride with either sulphur dioxide or arsenic(III) oxide lead to mixtures of rhenium(VI) oxide tetrachloride and rhenium(III) chloride. With anhydrous tin(II) chloride the pentachloride is quantitatively reduced to the trichloride. The pentachloride is reduced by 2,2′-bipyridyl(bipy) to give ReCl4(bipy), and ammonolysis occurs with liquid ammonia to give [ReCl3(NH2)2,2NH3]n. The oxopentabromorhenate(V) ion results from the reaction of the pentachloride with 48% hydrobromic acid.Keywords
This publication has 0 references indexed in Scilit: