Stereochemistry of the nickel-catalysed hydrocyanation of olefins
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 1098-1099
- https://doi.org/10.1039/c39810001098
Abstract
Nickel-catalysed addition of deuterium cyanide to (E)-1-deuterio-3,3-dimethylbut-1-ene (1) and subsequent analysis of the dideuteriated nitrile (2) by 1H n.m.r. spectroscopy shows that the addition of deuterium and cyanide occurs in a cis-fashion.Keywords
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