Zinc and Cadmium Derivatives of Tris(1-Pyrazolyl)Methane
- 1 December 1987
- journal article
- research article
- Published by Taylor & Francis in Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
- Vol. 17 (10) , 909-922
- https://doi.org/10.1080/00945718708059486
Abstract
Tris(1-pyrazolyl)methane, L, gives thermally stable LMX2, L2MI2, and octahedral [L2M]Z2 species, where M is zinc or cadmium, X may be Cl, Br, I, or trifluoroacetate, and Z is perchlorate or tetrafluoroborate. Conductivity, infrared, and nmr spectra (1H and 13C), show that these compounds are not stable in the few solvents in which they dissolve, i.e. dimethylsulphoxide and, to a lesser extent, methanol due to ligand displacement.Keywords
This publication has 7 references indexed in Scilit:
- Tin(IV) and organotin(IV) adducts of bis(1-pyrazolyl)methaneInorganica Chimica Acta, 1987
- The Coordination Chemistry of Pyrazole‐Derived LigandsPublished by Wiley ,1986
- On the interaction between mercury(II) cyanide, or chloride, and diazolesInorganica Chimica Acta, 1984
- On the interaction between mercury(II) thiocyanate, perchlorate or acetate and various diazoles and triazolesInorganica Chimica Acta, 1984
- IMPROVED SYNTHESIS OF POLYAZOLYLMETHANES UNDER SOLID-LIQUID PHASE-TRANSFER CATALYSISOrganic Preparations and Procedures International, 1984
- Synthetic and X-ray structural studies of complexes formed by metallation of tri(1-pyrazolyl)methane by dimethylplatinum(II)J. Chem. Soc., Dalton Trans., 1983
- N ‐Tripyrazolyl‐methanBerichte der deutschen chemischen Gesellschaft (A and B Series), 1937