Different crystal structures of inclusion complexes formed by syn-2,syn-7-dihydroxy-2,7-dimethyltricyclo[4.3.1.13,8]undecane with ethyl acetate and benzene
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 16,p. 889-891
- https://doi.org/10.1039/c39830000889
Abstract
X-Ray structure determinations show that crystals of syn-2,syn-7-dihydroxy-2,7-dimethyltricyclo[4.3.1.13,8]undecane obtained from ethyl acetate solution possess a spontaneously resolved trigonal network of helical canals containing mobile solvent, while crystals of the same compound obtained from benzene are racemic and tetragonal with the solvent trapped in ellipsoidal cavities.Keywords
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