Rearrangements of ethylene oxide derivatives. V. The boron trifluoride catalysed rearrangement of some 1,1-disubstituted ethylene oxides
- 1 January 1970
- journal article
- Published by CSIRO Publishing in Australian Journal of Chemistry
- Vol. 23 (10) , 2077-2084
- https://doi.org/10.1071/ch9702077
Abstract
The boron trifluoride catalysed rearrangement of the unsymmetrical epoxide (3) to give aldehyde (5) proceeds by selective (c. 1.9: 1) migration of the hydrogen atom (Hb) cis to the methyl group.Keywords
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