Fluorovinylation of Aldehydes and Ketones Using 2-(Diphenylmethylsilyl)-1- fluoro-1-(phenylsulfonyl)ethane
- 1 January 1994
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1994 (09) , 725-726
- https://doi.org/10.1055/s-1994-22986
Abstract
The carbanion derived from the title ß-silylsulfone reacts with aldehydes and ketones readily to afford fluoro olefins, which was produced via desulfination of initially formed adducts with concomitant 1,4-migration of the diphenylmethylsilyl group from the carbon to the oxygen atom.Keywords
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