Sulphur extrusion. Part 4. A halogen-catalysed conversion of thiocarbonyl compounds into their corresponding oxygen analogues using alkoxides and hydroxide
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- p. 2647-2649
- https://doi.org/10.1039/p19810002647
Abstract
The conversion of thiocarbonyl compounds (thioureas, thioamides, and thiones) into their oxygen analogues has been performed using either (i) potassium t-butoxide with iodine, bromine, or chlorine, (ii) sodium ethoxide with bromine or chlorine, or (iii) sodium hydroxide with bromine or chlorine under phase transfer catalysis.Keywords
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