Thermochemistry of aluminium halide–pyridine complexes
- 1 January 1968
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 316-317
- https://doi.org/10.1039/j19680000316
Abstract
The heats of formation of the crystalline adducts C5H5N,AlCl3, 2C5H5N,AlCl3, 3C5H5N,AlCl3, C5H5N,All3, and 3C5H5N,All3 have been determined calorimetrically. Vapour pressure measurements on the 1:1 complexes have enabled gas-phase heats of formation and dissociation energies to be calculated. The halide series are discussed and compared with other Group III systems.Keywords
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