Z-chlorination of alkylphenylacetylenes with antimony pentachloride

1 January 1976

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 4,p. 145
https://doi.org/10.1039/c39760000145

Abstract

Reaction of alkylphenylacetylenes with SbCl₅ in carbon tetrachloride gives the corresponding dichloroalkenes in fair yields, Z-addition predominating.

Keywords

Z CHLORINATION
ALKYLPHENYLACETYLENES
CORRESPONDING DICHLOROALKENES
CARBON TETRACHLORIDE
ANTIMONY PENTACHLORIDE
FAIR YIELDS
PENTACHLORIDE REACTION
ADDITION PREDOMINATING

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