A NMR and Mössbauer study of Nd2Fe14B

Abstract
Mössbauer spectroscopy and spin echos nuclear magnetic resonance were used in order to study the hyperfine fields (HF) at the six Fe sites and the B site in Nd2Fe14B. At 4.2 K hyperfine fields and Fe magnetic moments for the different sites in the range 307–372 kOe and respectively 2.05–2.48 μB have been found. The transferred HF of 31.25 kOe at the B site has a strong local character, being determined by the six next‐nearest Fe atoms in the corner of the trigonal prism in which B atoms are located.

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