Double silylation of allene and buta-1,2-diene: formation of new organosilicon compounds containing both vinylsilane and allylsilane units
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 12,p. 617-618
- https://doi.org/10.1039/c39810000617
Abstract
Addition of chloromethyl-and methoxymethyl-disilanes, as well as hexamethyldisilane, to allene and buta-1,2-diene in the presence of a Pd (PPh3)4 catalyst gave, regioselectively, new functionalized organosilicon compounds, 2,3-bis(organosily)prop-1-enes and 2,3-bis-(organosilyl)but-1-enes, respectively.Keywords
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