Exciton–Exciton Interaction and Optical Gain in Colloidal CdSe/CdS Dot/Rod Nanocrystals

Abstract
Exciton–exciton interaction in dot/rod CdSe/CdS nanocrystals has proved to be very sensitive to the shape of nanocrystals, due to the unique band alignment between CdSe and CdS. Repulsive exciton–exciton interaction is demonstrated, which makes CdSe/CdS dot/rods promising gain media for solution-processable lasers, with projected pump threshold densities below 1 kW cm−2 for continuous wave lasing.
Funding Information
  • Italian MIUR
  • INFM-CNR Seed project for young researchers
  • FIRB-MIUR project (Synergy-FIRBRBNE03S7XZ)
  • Human Potential Programs (RTN Nanomatch) (MRTN-CT-2006-035884)
  • Austrian Nano-Initiative (project NSI)
  • Austrian Science Fund FWF (START Y179)