Three-co-ordinated transition-metal compounds. Part II. Electronic spectra and magnetism of tris(bistrimethylsilylamido)derivatives of scandium, titanium, vanadium, chromium, and iron
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 2,p. 185-191
- https://doi.org/10.1039/dt9730000185
Abstract
The electronic spectra, magnetic susceptibilities, and preliminary e.s.r. data are reported for the trigonal compounds M[N(SiMe3)2]3 where M = Sc, Ti, V, Cr, and Fe. The data are interpreted on the basis of crystal-field calculations for dn systems in D3h symmetry.Keywords
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