Depth‐profiles and surface enrichment of the halogens in four Antarctic H5 chondrites and in two non‐Antarctic chondrites

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Abstract
Abstract— Depth‐profiles of F, Cl, Br and I concentrations were determined in four different Antarctic H5 chondrites from the Allan Hills and in the two chondrites Allende (C3) and Holbrook (L6). Pieces of the meteorites were studied by analysis of stepwise removed layers of 0.5–1.0 mm thickness up to a depth of 9 mm. Neutron activation analysis and ion‐selective potentiometry were used for the determination of Cl, Br, I and for F, respectively. The Antarctic meteorites show higher concentrations of the halogens at the surface compared to the interior. The highest enrichment factors are found for I and Cl and the lowest for Br. In contrast, F shows the steepest concentration gradient and is only enriched in the first 2.5 mm below the surface. The other halogens have penetrated deeper into the meteorites. The measured enrichments at the surfaces are not correlated to the visible degree of weathering. The analysed non‐Antarctic meteorites, which were recovered shortly after their observed fall, demonstrate similar halogen concentrations at the surface, including the fusion crust, as in the interior. Based on these results we present a model to estimate the degree of contamination and the relation to the duration of exposure at the surface of the Antarctic ice.