VOLUME EFFECTS PRODUCED BY THE COORDINATION OF Zn(II) TO POLYFUNCTIONAL ORGANIC ACIDS
- 1 January 1978
- journal article
- research article
- Published by Taylor & Francis in Journal of Coordination Chemistry
- Vol. 7 (3) , 149-153
- https://doi.org/10.1080/00958977808073054
Abstract
To interpret the volume changes, A V, produced by the interaction of Zn(I1) with proteins the values for the δ V of coordination of Zn(I1) with the specific ligands must be known. This consideration provided the impetus for determining the δV for the formation of 1 : 1 Zn(I1): poly-functional acid complexes. The data for monocarboxylates are omitted because the reactions do not go to completion.1,2 Water and 8.00 M urea were employed as solvents to establish medium effects.Keywords
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