Thermodynamic considerations in co-ordination. Part XV. Potentiometric and calorimetric study of the complexes formed between protons, first transition series metal ions, and asparaginate and glutaminate anions
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 11,p. 1117-1120
- https://doi.org/10.1039/dt9740001117
Abstract
ΔG°, ΔH°, and ΔS° for the asparaginate –H+, MnII, FeII, CoII, NiII, and ZnII, and for the glutaminate –H+, NiII, and CuII systems are reported for aqueous solution studies at 25 °C and I= 3·00M(Na+) ClO4 –. The results are used to calculate that quite a large proportion of asparaginate in blood plasma may be complexed to ZnII, FeII, and CoII, as well as to the expected CuII.Keywords
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