Chemoselective Oxidation ofAlcohols to Aldehydes and Ketones by Iodosobenzene/(Salen)Chromium Complex
- 24 July 2003
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 2003 (10) , 1391-1394
- https://doi.org/10.1055/s-2003-40852
Abstract
Various benzylic and allylic alcohols were selectively oxidized to their corresponding aldehydes and ketones by a new Cr(III)(salen) complex I as the catalyst and PhIO as terminal oxidant. The oxidation requires relatively shorter reaction time and produces excellent yields.Keywords
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