Synthesis and aggregation properties of novel soluble ‘crowned’ metallotriazolehemiporphyrazines

Abstract
Synthesis and preliminary studies on the aggregation and non-linear optical properties of novel, highly soluble, free and transition metal-complexed triazolehemiporphyrazines 1 containing two 15-crown-5 subunits are reported; aggregation of the ‘crowned’ metallotriazolehemiporphyrazines induced by alkali cations is observed for the first time in these kinds of compounds.

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