Iridium(I)-catalysed asymmetric hydrosilylation of ketones using a chiral oxazolylferrocene-phosphine hybrid ligand
- 1 January 1996
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 7,p. 847-848
- https://doi.org/10.1039/cc9960000847
Abstract
The chiral oxazolylferrocene-phosphine hybrid ligand(DIPOF) is a very effective ligand for IrI-catalysed asymmetric hydrosilylation of simple ketones to give the corresponding sec-alcohols(up to 96% ee) after acid hydrolysis.Keywords
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