A molecular photoswitch based on an ‘axial-bonding’ type phosphorus(v) porphyrin

Abstract
Reversible isomerization of the two axial azobenzene subunits leads to modulation of the fluorescence due to the basal tetrapyrrolic chromophore in a new hexa-coordinated phosphorus(V) porphyrin 3, illustrating its utility as a molecular photoswitch.

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