Two-dimensional metamagnet composed of cyano-bridged CuII–WVbimetallic assembly
- 20 October 2003
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 22,p. 2772-2773
- https://doi.org/10.1039/b310456g
Abstract
Two-dimensional cyanide-bridged copper(II) octacyanotungstates(V), [{Cu(3-CNpy)2(H2O)}2{Cu(3-CNpy)2(H2O)2}{W(CN)8}2] (3-CNpy = 3-cyanopyridine) (1) and [{Cu(4-CNpy)2}2{Cu(4-CNpy)2(H2O)2}{W(CN)8}2]·6H2O (4-CNpy = 4-cyanopyridine) (2), were prepared and these compounds exhibited metamagnetic behavior with Néel temperatures of 8.0 K (1) and 4.4 K (2).Keywords
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