Pulse-to-pulse normalization of time-resolved Fourier transform emission experiments in the near infrared
- 1 April 1995
- journal article
- conference paper
- Published by AIP Publishing in Review of Scientific Instruments
- Vol. 66 (4) , 2812-2817
- https://doi.org/10.1063/1.1145560
Abstract
The signal-to-noise ratio in a time-resolved Fourier transform (FT) infrared emission experiment is improved by pulse-to-pulse normalization. The signal from the FT spectrometer is normalized by the total infrared fluorescence produced on each laser pulse. A factor of 20 enhancement in signal-to-noise ratio is demonstrated with normalization when the fluctuation of the laser pulse energy is the dominant noise source. Applications are discussed pertaining to cases where other noise sources such as detector and amplifier noise cannot be neglected and when information from the time evolution of the spectrum is required.Keywords
This publication has 15 references indexed in Scilit:
- The effect of reagent translational excitation on the dynamics of the reaction H+Cl2→HCl(v′,J′)+ClThe Journal of Chemical Physics, 1994
- A laser flash photolysis, time-resolved Fourier transform infrared emission study of the reaction monochlorine + ethyl .fwdarw. hydrogen chloride(v) + etheneThe Journal of Physical Chemistry, 1993
- A laser flash photolysis/time-resolved FTIR emission study of a new channel in the reaction of methyl + oxygen atom: production of carbon monoxide(v)The Journal of Physical Chemistry, 1992
- Preferential in-plane rotational excitation of H2O (001) by translational-to-vibrational transfer from 2.2 eV H atomsThe Journal of Chemical Physics, 1992
- Photodissociation of ammonia at 193.3 nm: Rovibrational state distribution of the NH2(Ã 2A1) fragmentThe Journal of Chemical Physics, 1991
- Time-resolved FTIR emission studies of molecular photofragmentationAccounts of Chemical Research, 1989
- Photofragmentation of acetone at 193 nm: rotational- and vibrational-state distributions of the carbon monoxide fragment by time-resolved FTIR emission spectroscopyThe Journal of Physical Chemistry, 1988
- Rotationally resolved product states of polyatomic photofragmentation by time-resolved FTIR emission: HF elimination from 1,1-CH2CClF at 193 mmThe Journal of Chemical Physics, 1988
- The interaction of O(1D2) with HCl: The initial vibrational distributions in the OH(2Π) produced by chemical reaction, and the HCl(1Σ+) produced by E–V energy transferThe Journal of Chemical Physics, 1988
- The dynamics and microscopic kinetics of the reactions of O(1D2) atoms with CHCl3 and CHF3The Journal of Chemical Physics, 1987