A novel rearrangement in a 1,3-bishomocubyl ring system
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 14,p. 1108-1109
- https://doi.org/10.1039/c39870001108
Abstract
When treated with potassium ferricyanide–sodium nitrite in the presence of base, methyl 3,10-dinitropentacyclo-[5.3.0.02,5.O3,9.O4,8]decane-1-carboxylate undergoes an unusual skeletal rearrangement to afford methyl 3,9-dinitro-exo-10-methoxypentacyclo[5.3.0.02,5.03,9.04,8]decane-8-carboxylate whose structure was confirmed via single crystal X-ray crystallographic analysis.Keywords
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