Synthesis and Characterization of Fe(II), Co(II), Ni(II) and Cu(II) Complexes with Bromazepan, An Anxiolytic Drug. Part III. Thiocyanate Complexes
- 1 January 1986
- journal article
- research article
- Published by Taylor & Francis in Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
- Vol. 16 (1) , 13-19
- https://doi.org/10.1080/00945718608055906
Abstract
A series of Bromazepan (B) complexes of Fe(II), Co(II), Ni(II) and Cu(II) thiocyanates of the type MB2(SCN)2 have been prepared. Physicochemical characterization of the complex species have been made from magnetic susceptibility measurements, electronic, vibrational and e.s.r. spectra. Magnetic and electronic spectral features suggest a pseudo-octahedral environment of the central M(II) ion in all these complexes. IR spectra have furnished positive information regarding bonding sites of the ligand molecule and the mode of the attachment of the SCN− to metal ion.Keywords
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