The Reaction of Hydrogen Atoms with Carbon Tetrachloride
- 1 December 1938
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 6 (12) , 811-818
- https://doi.org/10.1063/1.1750175
Abstract
Reaction rate constants have been obtained at seven temperatures between 21° and 200° for the reaction H+CCl4=HCl+CCl3. The change of reaction rate with temperature is satisfactorily represented by the classical bimolecular reaction theory with a steric factor of 0.007 and an activation energy of 3.45 kcal. per mole. A comparison of the amount of HCl formed with the number of hydrogen atoms entering indicates that complete conversion of atomic hydrogen into HCl by the reaction may be attained at 150–200° under conditions which are determined in the experiments.Keywords
This publication has 7 references indexed in Scilit:
- Atomic hydrogen - I—The calorimetry of hydrogen atomsProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1937
- Viscosity of Deuterium1Journal of the American Chemical Society, 1935
- The recombination of hydrogen atomsTransactions of the Faraday Society, 1935
- Die theoretische Behandlung chemischer Reaktionen in strömenden SystemenAnnalen der Physik, 1934
- The Reactions of Atomic Hydrogen with Several Alkyl HalidesJournal of the American Chemical Society, 1933
- THE HEAT OF FORMATION OF MOLECULAR HYDROGEN1Journal of the American Chemical Society, 1928
- THE ENTROPY OF HYDROGEN CHLORIDE. HEAT CAPACITY FROM 16°K. TO BOILING POINT. HEAT OF VAPORIZATION. VAPOR PRESSURES OF SOLID AND LIQUIDJournal of the American Chemical Society, 1928