A novel, internally-solvated phosphinomethanide; crystal structure of Li[C(SiMe3)2{P(C6H4CH2NMe2-2)2}]
- 1 January 1998
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 10,p. 1129-1130
- https://doi.org/10.1039/a801342j
Abstract
Metallation of P{CH(SiMe3)2}(C6H4CH2NMe2-2)2 with BunLi yields a novel lithium phosphinomethanide in which the ligand exhibits an unprecedented tridentate PN2 coordination mode and in which there are no short contacts between lithium and the planar carbanion centre.Keywords
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