A triply-bridged binuclear hydrazidomolybdenum(V) complex with terminal, bridging, and ‘dangling’ thiolate ligands. The chemical and structural characterization of [HNEt3]2[Mo2(NNPh)(NNHPh)(SCH2CH2S)3(SCH2CH2SH)]·2/3H2NNHPh
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 17,p. 1172-1174
- https://doi.org/10.1039/c39840001172
Abstract
The title compound has been obtained by treating [Mo(NNHPh)2(butane-2,3-diolate)2]·H2NNHPh with excess of dimercaptoethane in methanol; X-ray crystallography reveals the first example of a binuclear bis-hydrazido complex and a unique instance of a molybdenum(V) complex exhibiting thiolate co-ordination trans to a strongly π-bonding group.Keywords
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