Fukinotoxin, a new pyrrolizidine alkaloid from Petasites japonicus.

Abstract
Fukinotoxin (I), a novel pyrrolizidine alkaloid, was isolated from young scape of P. japonicus; its structure was shown to be (12R,13R,15R,3''R)-12-hydroxy-4,12,13-trimethyl-4,8-secosenec-1-enine-15-spiro-2''-(3''-methyl)oxiran with the aid of chemical and X-ray crystallographic analyses.

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