Construction of a sterically congested carbon framework via 5-hexenyllithium cyclization. Synthesis of (±)-cuparene.
- 1 September 1991
- journal article
- Published by Elsevier in Tetrahedron
- Vol. 47 (37) , 7727-7738
- https://doi.org/10.1016/s0040-4020(01)81931-1
Abstract
No abstract availableThis publication has 19 references indexed in Scilit:
- Formation of a -bicyclo[3.3.0]Octane by tandem anionic cyclization: evidence for the highly stereoselective irreversible nature of 5-hexen-1-yllithium cyclizationsTetrahedron Letters, 1990
- Preparation of 1-substituted bicyclo[2.2.1]heptanes by anionic cyclization of a 5-hexen-1-yllithiumThe Journal of Organic Chemistry, 1990
- A New Route to Compounds Bearing Two Contiguous Quaternary CentresSynlett, 1990
- Reductive lithiation mediated anionic cyclizations and [2,3]-sigmatropic rearrangementsJournal of the American Chemical Society, 1989
- Tandem anionic cyclization approach to polycarbocyclic productsJournal of the American Chemical Society, 1989
- Vinyllithium cyclizations with unactivated alkenes as internal electrophiles: stereoselective formation of substituted methylenecyclopentanesJournal of the American Chemical Society, 1988
- Preparation and regiospecific cyclization of alkenyllithiumsJournal of the American Chemical Society, 1987
- Lithium-halogen exchange-initiated cyclization reactions. 3. Intramolecular conjugate addition reactions of unsaturated acylphosphoranesThe Journal of Organic Chemistry, 1987
- Cyclization of 5-hexenyllithium to (cyclopentylmethyl)lithiumThe Journal of Organic Chemistry, 1985
- The chemistry of the natural order cupressales—XXITetrahedron, 1958