Fourier transform spectroscopy of the ν3 band of the N3 radical
- 15 August 1988
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 89 (4) , 1762-1767
- https://doi.org/10.1063/1.455122
Abstract
We have analyzed the ν3 antisymmetric stretching fundamental of the N3 radical. Azide radicals N3 were generated in a multipass cell by the reaction of Cl atoms and HN3 and detected in absorption using a Fourier transform spectrometer. Improved constants for the 000 vibrational level of X̃ 2Πg are reported along with observations of the 001 level. The frequency of the ν3 fundamental at 1645 cm−1 was found to be somewhat lower than expected.Keywords
This publication has 31 references indexed in Scilit:
- Velocity modulation infrared laser spectroscopy of negative ions: The ν3, ν3+ν1−ν1, ν3+ν2−ν2, and ν3+2ν2−2ν2 bands of cyanate (NCO−)The Journal of Chemical Physics, 1987
- Velocity modulation laser spectroscopy of negative ions. The .nu.3 band of azide anionJournal of the American Chemical Society, 1987
- The P(4Su) + N3(2IIg) reaction: chemical generation of a new metastable state of PNThe Journal of Physical Chemistry, 1987
- Product analysis of the hydroxyl + nitrogen dioxide + M reactionThe Journal of Physical Chemistry, 1987
- Multibody analysis of potential energy surfaces for first‐ and second‐row tetramers. I. The tetrahedral structures of P4 and N4International Journal of Quantum Chemistry, 1984
- Heterodyne frequency measurements on the 116-μm band of OCS: new frequency/wavelength calibration tables for 116- and 58-μm OCS bandsApplied Optics, 1981
- Azide mechanisms for the production of NCl metastablesInternational Journal of Chemical Kinetics, 1980
- The emission spectrum of the CO2+ ion: rovibronic analysis of the band systemCanadian Journal of Physics, 1979
- The Emission Spectrum of the CO2+ Ion: Band SystemCanadian Journal of Physics, 1975
- The detection of free radicals in the high intensity photolysis of hydrogen azideProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1956