Solid Fluorine and Solid Chlorine: Crystal Structures and Intermolecular Forces
- 1 June 1968
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 48 (11) , 4890-4895
- https://doi.org/10.1063/1.1668152
Abstract
Extended Hückel molecular‐orbital (EHMO) calculations and molecular multipole sums are compared for various assemblies of Cl2 molecules. It is shown that the multipole sums does not predict the correct space group for Cl2 but that the EHMO calculation does, if there is d‐orbital involvement. Some comments are made on the crystal structures of α‐ and of β‐F2, both different from those of the other halogens.Keywords
This publication has 19 references indexed in Scilit:
- Antiferromagnetic and Crystal Structures of Alpha-OxygenThe Journal of Chemical Physics, 1967
- On the Nature of Forces in Solid ChlorineJournal of the Physics Society Japan, 1965
- Crystal and Molecular Structure of Diboron Tetrafluoride, B2F4The Journal of Chemical Physics, 1958
- The crystal structure of solid chlorineActa Crystallographica, 1956
- The Structures of the Interhalogen Compounds. I. Chlorine Trifluoride at −120°CThe Journal of Chemical Physics, 1953
- The crystal structure of solid chlorineActa Crystallographica, 1952
- Nuclear Quadrupole Effects and Electronic Structure of Molecules in the Solid StateThe Journal of Chemical Physics, 1952
- THE RAMAN SPECTRUM OF FLUORINECanadian Journal of Physics, 1951
- The Structure of Crystalline BromineJournal of the American Chemical Society, 1936
- THE ATOMIC ARRANGEMENT IN THE CRYSTAL OF ORTHORHOMBIC IODINEJournal of the American Chemical Society, 1928