Optically active spiro[4.4]nonane derivatives: syntheses and circular dichroism of βγ-unsaturated ketones
- 1 January 1977
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 15,p. 542-543
- https://doi.org/10.1039/c39770000542
Abstract
(+)-6-Methylenespiro[4.4]nonan-1-one (6) and (–)-spiro[4.4]non-6-en-1-one (10) were prepared by synthetic methods establishing the absolute configuration of each, and anti-octant behaviour was observed in the c.d. spectra of (10).Keywords
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