Bivalent Copper Ion Complex of a Novel Anionic Surfactant Having Functional Imidazole and Hydroxyl Groups as a Remarkably Active Model of Hydrolytic Metalloenzymes
- 5 June 1988
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 17 (6) , 981-984
- https://doi.org/10.1246/cl.1988.981
Abstract
A novel anionic surfactant having functional imidazole and hydroxyl groups, Sodium N-dodecyl-2,5-dihydroxymethyl-4-(2-thiomethylethanesulfonate)imidazole, was synthesized. This surfactant was found to be remarkably active in the acyl transfer reactions of p-nitrophenyl picolinate in the presence of Cu2+ ion under micellar conditions.Keywords
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