Modern He–He potentials: Another look at binding energy, effective range theory, retardation, and Efimov states
- 8 December 1995
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 103 (22) , 9626-9630
- https://doi.org/10.1063/1.469978
Abstract
We compare a number of helium–helium potentials with respect to their predictions of dimer binding energy, scattering length, effective range and Efimov states. We also study the effect of retardation on the ‘‘best’’ potential. All realistic potentials support a weakly bound dimer, while none supports an Efimov state. We agree with other authors that retardation decreases the binding energy by about 10%. Finally, we investigated the effect on the binding energy from the application of retardation over different ranges of separation. The precise effects of retardation at short range in realistic potentials require further study.Keywords
This publication has 44 references indexed in Scilit:
- Benchmark full configuration interaction calculations on the helium dimerThe Journal of Chemical Physics, 1995
- Retarded dipole-dipole dispersion interaction potential for heliumPhysical Review A, 1995
- Accurate Analytical He-He van der Waals Potential Based on Perturbation TheoryPhysical Review Letters, 1995
- A new determination of the ground state interatomic potential for He2Molecular Physics, 1987
- The He2 potential at small distancesThe Journal of Chemical Physics, 1986
- Ab initio evaluation of multipole dispersion energies and propertiesThe Journal of Physical Chemistry, 1982
- Determination of the-Repulsive Potential up to 0.14 eV by Inversion of High-Resolution Total—Cross-Section MeasurementsPhysical Review Letters, 1973
- The dipole spectrum and properties of heliumProceedings of the Physical Society, 1965
- Calculation of the van der Waals force constant from oscillator strength sumsProceedings of the Physical Society, 1965
- On the perturbation theory of small disturbancesProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1956