Cation-radicals: tris-(p-bromophenyl)amminium perchlorate and hexachloroantimonate

1 January 1969

journal article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society C: Organic

No. 20,p. 2719-2720
https://doi.org/10.1039/j39690002719

Abstract

Stable triarylamminium salts may be used as convenient one-electron oxidants for a range of organic molecules. Synthesis and characterisation of perchlorate and hexachloroantimonate salts of the tris-(p-bromophenyl)amminium cation [(p-BrC₆H₄)₃N⁺] are described in detail. The hexachloroantimonate is easier to prepare and is much the more stable, both thermally and photochemically.

Keywords

SALTS
HEXACHLOROANTIMONATE
RADICALS
BROMOPHENYL
TRIS
AMMINIUM
PERCHLORATE
PHOTOCHEMICALLY
CONVENIENT
THERMALLY

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