Allene transfer reactions. A new synthesis of terminal allenes
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 19,p. 1284-1285
- https://doi.org/10.1039/c39840001284
Abstract
Alkyl radicals, produced from alkyl bromides and iodides, react smoothly with triphenylprop-2-ynylstannane to provide terminal allenes; this new reaction has been applied to a simple and stereospecific synthesis of the naturally occurring allenic amino-acid, S-2-aminohexa-4,5-dienoic acid.Keywords
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